• 文献标题:   Direct Electrodeposition to Fabricate Vertically-Oriented Graphene Nanosheets Modified Electrode and its Application for Determination of Levodopa in the Presence of Uric Acid and Ascorbic Acid
  • 文献类型:   Article
  • 作  者:   WU YJ, SONG HJ, LU K, YE Y, LV MX, ZHAO YF
  • 作者关键词:   graphene oxide, pulse potential method, ldopa, voltammetric sensor
  • 出版物名称:   NANO
  • ISSN:   1793-2920 EI 1793-7094
  • 通讯作者地址:   Henan Univ Engn
  • 被引频次:   3
  • DOI:   10.1142/S1793292017500874
  • 出版年:   2017

▎ 摘  要

The electrodeposition of reduced graphene oxide (rGO) film with preferred vertical orientation was fabricated on a glassy carbon electrode by using pulse potential method in a graphene oxide solution. The rGO film was applied in developing a high-sensitive electrochemical sensor for detection of levodopa (L-dopa). The new electrochemical sensor displayed a significant response to L-dopa because of its excellent electric conductivity and large specific surface area. Moreover, the determination of L-dopa on this modified electrode was not interfered by the coexistence of ascorbic acid (AA) and uric acid (UA). Under the selective conditions, the modified electrode showed a linear voltammetric response to L-dopa within a certain concentration ranging from 5.0 x 10(-7) 1.5 x 10(-4) mol L-1, with the detection limit of 1.0 x 10(-7) mol L-1. Besides, the modified electrode also exhibited an excellent selectivity, stability, reproducibility and repeatability.