• 文献标题:   Rolling up a Graphene Sheet
  • 文献类型:   Review
  • 作  者:   CALVARESI M, QUINTANA M, RUDOLF P, ZERBETTO F, PRATO M
  • 作者关键词:   folding, graphene, nanotube, rolling, ultrasonication
  • 出版物名称:   CHEMPHYSCHEM
  • ISSN:   1439-4235 EI 1439-7641
  • 通讯作者地址:   Univ Bologna
  • 被引频次:   25
  • DOI:   10.1002/cphc.201300337
  • 出版年:   2013

▎ 摘  要

Carbon Nanotubes, CNTs, have been described as rolled-up graphene layers. Matching this concept to experiments has been a great experimental challenge for it requires a method to exfoliate graphite, generate ordered and stable dangling carbon bonds, and roll up the layer without affecting the un-paired electrons of the dangling bonds that finally have to zip up in an orderly fashion: A tall order for any synthetic strategy. The combined use of ultrasonication of graphite in dimethylformamide and addition of ferrocene aldehyde just does it!