• 文献标题:   Hindering effect of graphene oxide on reaction performance of Al/MnO2 nanothermite system
  • 文献类型:   Article
  • 作  者:   SONG JX, GUO T, YAO M, CHEN JL, DING W, ZHANG XN, BEI FL, HUANG JY
  • 作者关键词:   graphene oxide, nanocomposite, ignition resistance, hindering effect
  • 出版物名称:   COLLOID INTERFACE SCIENCE COMMUNICATIONS
  • ISSN:   2215-0382
  • 通讯作者地址:   Army Engn Univ PLA
  • 被引频次:   0
  • DOI:   10.1016/j.colcom.2020.100271
  • 出版年:   2020

▎ 摘  要

Graphene oxide (GO) with outstanding mechanical properties and high temperature stability is attractive to many researchers. As a flame retardant, GO also has been widely used in fire resistance applications of polymers. Herein, to explore ignition resistance effect of GO on nanothermite, GO/Al/MnO2 nanocomposites were pre-pared. Due to the large specific surface area, GO can completely cover the surface of nanothermite components. Thermal results showed that exothermic thermite reaction occurred in the range of 500 degrees C to 600 degrees C while with GO addition, thermite reaction did not happen at all. Originally, combustion phenomenon of Al/MnO2 na-nothermite was intense with bright flame, but GO/Al/MnO2 nanocomposites cannot be ignited even if the current on heating wires was higher. The physical barrier of GO hinders the direct contact between fuel and oxidizer which prevents the occurrence of self-propagating thermite reaction. This work provides guiding sig-nificance to the design of nanothermite flame retardant.