• 文献标题:   High-performance Forster resonance energy transfer-based dye-sensitized photocatalytic H-2 evolution with graphene quantum dots as the homogeneous energy donor
  • 文献类型:   Article
  • 作  者:   LEI YG, XUE Y, LI YA, LIU XY, WANG F, MIN SX
  • 作者关键词:  
  • 出版物名称:   PHOTOCHEMICAL PHOTOBIOLOGICAL SCIENCES
  • ISSN:   1474-905X EI 1474-9092
  • 通讯作者地址:   North Minzu Univ
  • 被引频次:   2
  • DOI:   10.1039/c8pp00227d
  • 出版年:   2018

▎ 摘  要

A high-performance dye-sensitized photocatalytic H-2 evolution system was developed based on Forster resonance energy transfer (FRET) by employing water-soluble and highly photoluminescent N,S codoped graphene quantum dots (NSGQDs) as the homogeneous energy donor, erythrosin B (ErB) as the sensentizing dye, and platinum nanoparticles (Pt NPs) as the catalyst. NSGQDs absorbed high-energy photons that undergo FRET to transfer the excitation energy to the sensitizing ErB for maximizing light absorption and also served as an electron transfer and loading matrix of Pt NPs for accelarating the electron transfer; as a result, the ErB-sensitized NSGQD-Pt system afforded much higher H-2 evolution activity than the NSGQD-free dye-sensitized system.