• 文献标题:   Enhancement in the Specific Energy of B-doped Graphene Using Redox Additive Electrolytes
  • 文献类型:   Article
  • 作  者:   BALAJI SS, TAUQUIR SM, KARNAN M, MOORTHY M, SATHISH M
  • 作者关键词:   bdoped graphene, supercritical fluid, redox additive, supercapacitor
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Cent Electrochem Res Inst
  • 被引频次:   0
  • DOI:   10.1002/slct.202002548
  • 出版年:   2020

▎ 摘  要

Electrochemical performance of carbon materials can be enhanced by doping with heteroatoms. Electrochemical investigations suggest that the B-doped graphene in which B-source and graphene oxide are in the ratio 1 : 1 demonstrates a highest specific capacitance of 406 F/g at 2 A/g in 1 M H2SO4. The specific capacity of B-doped graphene in 0.01 M hydroquinone (HQ)/H(2)SO(4)is 2523 C/g in redox additive electrolyte. Performance evaluation of fabricated symmetric supercapacitor cell indicates that the specific capacitance in 0.01 M HQ/H(2)SO(4)and 1 M H(2)SO(4)solution are found to be 440 and 284 F/g at 3 A/g, respectively and greater than EMIMBF4(97 F/g). The maximum specific energy of the fabricated symmetric cell achieved using 0.01 M HQ/H(2)SO(4)solution is found to be 50 Wh/kg which is comparatively superior than 1 M H2SO4(14.2 Wh/kg) and EMIMBF4(30 Wh/kg).