• 文献标题:   Synthesis of Nitrogen and Phosphorus Dual-Doped Graphene Oxide as High-Performance Anode Material for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   WANG K, LI Z
  • 作者关键词:   graphene oxide, dualdoped, lithiumion battery, anode material
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Jiaozuo Power Supply Co
  • 被引频次:   0
  • DOI:   10.1166/jnn.2020.18872
  • 出版年:   2020

▎ 摘  要

Nitrogen and phosphorus dual-doped graphene oxide was prepared by directly calcining a mixture of pure graphene oxide, urea (nitrogen source), and 1,2-bis(diphenylphosphino)methane (phosphorous source). The morphology and composition of the obtained dual-doped graphene oxide were confirmed by SEM, TEM, XRD pattern, Raman spectrum, and XPS. The nitrogen and phosphorous dual-doped graphene oxide was tested as an anode material of lithium-ion batteries (LIBs). The cycle and rate performance of the dual-doped graphene oxide were also examined. The dual-doped graphene oxide exhibited a superior initial discharge capacity of 2796 mAh . g(-1) and excellent reversible capacity of 1200 mAh . g(-1) at a current density of 100 mA . g(-1) after 200 charge/discharge cycles, suggesting that the dual-doping of nitrogen and phosphorous is an effective way to enhance lithium-ion storage for graphene oxide.