• 文献标题:   Synthesis of potential antioxidants by synergy of ultrasound and acidic graphene nanosheets as catalyst in water
  • 文献类型:   Article
  • 作  者:   NAEIMI H, GOLESTANZADEH M, ZAHRAIE Z
  • 作者关键词:   graphene, green chemistry, ultrasound, antioxidant, solid acid
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:   Univ Kashan
  • 被引频次:   12
  • DOI:   10.1016/j.ijbiomac.2015.11.058
  • 出版年:   2016

▎ 摘  要

Efficient synthesis of a set of bisphenolic compounds, resulting from the incorporation of 2,4-dialkylphenols and aromatic or aliphatic aldehydes, allowed the discovery of new bisphenols with relative modest to good antioxidant activity. Bisphenolic compounds were prepared via easy and simple approach under ultrasound irradiation in water. Sulfonated graphene nanosheets were employed as a catalyst for the synthesis of bisphenolic compounds. These compounds were obtained in high to excellent yields (88-98%) and relatively short reaction times (4-20 min). Moreover, some of the synthetic compounds were investigated and revealed outstanding antioxidant activity, when examined by a 1,1-diphenyl-2-picryihydrazyl radical (DPPH) decolorization assay system. The proposed method has a novel viewpoint in the preparation of potential antioxidant compounds. (C) 2015 Elsevier B.V. All rights reserved.