• 文献标题:   Fabrication and investigation on Ag nanowires/TiO(2)nanosheets/graphene hybrid nanocomposite and its water treatment performance
  • 文献类型:   Article
  • 作  者:   LIU C, LIN Y, DONG YF, WU YK, BAO Y, YAN HX, MA JZ
  • 作者关键词:   tio 2 nanosheet, graphene, ag nanowire, adsorption, photocatalytic, molecular dynamics simulation
  • 出版物名称:   ADVANCED COMPOSITES HYBRID MATERIALS
  • ISSN:   2522-0128 EI 2522-0136
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1007/s42114-020-00164-2
  • 出版年:   2020

▎ 摘  要

In this paper, a novel Ag nanowires/TiO(2)nanosheets/graphene nanocomposite was fabricated via a facile method of hydrothermal and calcination, and then the water treatment performance of it was evaluated for methylene blue (MB) andEscherichia coliremoval. The as-prepared Ag nanowires/TiO(2)nanosheets/graphene nanocomposite was characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), UV-visible diffuse reflection spectroscopy (DRS), molecular dynamics simulation, and gas chromatography-mass spectrometry (GC-MS). All data revealed that the Ag/TiO2/graphene nanocomposite showed a rich cell structure. The photocatalytic activity of Ag/TiO2/graphene nanocomposite is higher than those of pristine TiO(2)nanosheets and TiO2/graphene nanocomposite. Under optimized conditions, the degradation efficiency was 100% and 71% for MB (30 mg/L) and with 10 mg Ag/TiO2/graphene nanocomposite under UV and visible light irradiation for 2 h, respectively. Ag/TiO2/graphene also showed excellent bacteria-killing activity. Meanwhile, the Ag/TiO2/graphene nanocomposite exhibited microstructure stability and cyclic stability. The water treatment performance was enhanced mainly attributed to the excellent adsorption performance of graphene and the high efficiency in separation of electron-hole pairs induced by the remarkable synergistic effects of TiO2, Ag, and graphene. On the basis of the experimental results, the photocatalytic mechanism and MB degradation mechanism were proposed. It is hoped that our work could avert the misleading message to the readership, hence offering a valuable source of reference on fabricating composite photocatalyst with stable microstructure and excellent performance for their application in the environment clean-up. Graphical abstract