• 文献标题:   Design and synthesis of novel binuclear ferrocenyl-intercalated graphene oxide and polyaniline nanocomposite for supercapacitor applications
  • 文献类型:   Article
  • 作  者:   PAYAMI E, AHADZADEH I, MOHAMMADI R, TEIMURIMOFRAD R
  • 作者关键词:   ferrocene, graphene oxide, pipi interaction, nanocomposite, batterytype supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Tabriz
  • 被引频次:   4
  • DOI:   10.1016/j.electacta.2020.136078
  • 出版年:   2020

▎ 摘  要

Various new nanohybrids consisting of 2,2-bis(ethylferrocenyl)propane [B-(EtFc)-Pr] as both battery-type electrode material and good candidate for intercalation between graphene oxide (GO) nanosheets, and GO as a substrate were prepared. According to the electrochemical experiments data, GO-B-(EtFc)-Pr3 nanohybrid with the weight ratio of GO:B-(EtFc)-Pr (1:3) was regarded as the optimum nanohybrid with excellent electrochemical performance. Then, GO-B-(EtFc)-Pr3/PANI nanocomposites with different amounts of polyaniline (PANI) were prepared and investigated by Fourier Transform Infrared Spectroscopy (FT-IR), Cyclic Voltammetry (CV), Galvanostatic Charge-Discharge measurement (GCD), Electrochemical Impedance Spectroscopy (EIS), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray (EDX) mapping, and X-ray Diffraction (XRD) analyses. Among different nanocomposites, GO-B-(EtFc)-Pr3/PANI0.5 exhibits a high charge storage capacity of 429 mAh g(-1) and excellent cycle life with charge storage capacity retention of 89.13% after 3000 CV cycles. (C) 2020 Elsevier Ltd. All rights reserved.