• 文献标题:   Monolayered graphene oxide as a barrier on polycrystalline copper substrate against thermal oxidation for a long duration
  • 文献类型:   Article
  • 作  者:   ANS M
  • 作者关键词:   graphene oxide go, thermal oxidation, copper oxide, raman spectroscopy
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.jelechem.2021.115526 EA JUL 2021
  • 出版年:   2021

▎ 摘  要

This work aimed to describe an innovative and economical method for coating copper with Graphene Oxide (GO) via dip coating and a study of the resulting barrier properties against oxidation. The thickness GO was found as an optimized thin film in the nanometer (0.5 -0.7 nm) range. The kinetics of thermal oxidation at low temperature (160 degrees C) is followed by an original procedure based on Raman spectroscopy. This approach permitted an unambiguous identification of cuprous oxide (Cu2O) on micron size regions and probed the measurement of the thin oxidized layer down to the nm scale. The findings showed that a monolayer of GO does not substantially alter oxidation kinetics at short times (similar to 1 h). Furthermore, it was found that GO film exhibited highly improved thermal oxidation stabilities due to remarkable gas barrier property. It remained an excellent candidate for passivation barrier and resistance to oxidation of copper since GO film significantly reduced the further propagation of the Cu2O layer at a long timescale (days) under the barrier film.