• 文献标题:   Solvothermal Synthesis of a Molybdenum Disulfide/Reduced Porous Graphene Oxide Nanocomposite as a High-Performance Anode Material for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   BAE Y, SEONG CY, YOO S, PARK SK, PIAO Y
  • 作者关键词:   electrochemistry, graphene, lithiumion batterie, molybdenum, nanocomposite
  • 出版物名称:   ENERGY TECHNOLOGY
  • ISSN:   2194-4288 EI 2194-4296
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   2
  • DOI:   10.1002/ente.201600502
  • 出版年:   2017

▎ 摘  要

Although molybdenum disulfide (MoS2) has a higher theoretical capacity than graphite as an anode material for lithium-ion batteries, its intrinsically poor electrical and ionic conductivity decrease its rate properties and lithium-storage capacity. In this work, we prepared a MoS2/reduced porous graphene oxide (rPGO) composite by the solvothermal method to complement the conductivity and to improve the lithium-storage properties of MoS2. PGO was synthesized by a convenient, low-costing, and mass-producible nitric acid treatment method. Owing to its large surface area and porous structure, the MoS2/rPGO sample exhibited improved capacity and cyclic stability over other MoS2/reduced graphene oxide (rGO) and MoS2 nanoparticle samples. After 100 cycles, the MoS2/rPGO electrode showed an improved capacity of 932 mAhg(-1), whereas the capacity of the MoS2/rGO electrode was 395 mAhg(-1) at a current density of 200 mAg(-1).