• 文献标题:   One-Pot Synthesis of Platinum Nanoparticles Embedded on Reduced Graphene Oxide for Oxygen Reduction in Methanol Fuel Cells
  • 文献类型:   Article
  • 作  者:   HA HW, KIM IY, HWANG SJ, RUOFF RS
  • 作者关键词:  
  • 出版物名称:   ELECTROCHEMICAL SOLID STATE LETTERS
  • ISSN:   1099-0062
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   62
  • DOI:   10.1149/1.3584092
  • 出版年:   2011

▎ 摘  要

A simple approach has been developed for the synthesis of Pt nanoparticles with uniform diameters of approximately 2.9 nm supported on reduced graphene oxide (RG-O) platelets via a modified polyol method. Compared to Johnson Matthey (JM) Pt/C (75 wt % Pt) catalyst, the Pt/RG-O (70 wt % Pt) composite showed much higher electrochemical surface area, greater catalytic activity towards the oxygen reduction reaction (ORR), and significantly better single cell polarization performance. The maximum power density of the Pt/RG-O composite was about 128 mW cm(-2), an 11% greater than the JM Pt/C commercial catalyst. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3584092] All rights reserved.