• 文献标题:   High corrosion resistance of reduced graphene oxide coated 316L stainless steel bipolar plate for proton exchange membrane fuel cell prepared by a facile method
  • 文献类型:   Article
  • 作  者:   YIN Q, WANG XW, LIU SY, WANG XZ, FU XZ, LUO JL
  • 作者关键词:   reduced graphene oxide, metallic bipolar plate, graphene oxideadsorbingh2 reducing method, corrosion resistance
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.matchemphys.2022.126663 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Metallic bipolar plate suffers corrosion attack in the harsh proton exchange membrane fuel cell (PEMFC) environments, which will lead to pronounced deterioration of the full cell output performance. Depositing a Graphene coating on the metallic bipolar plate surface is a promising approach to solving the problem. In this investigation, a facile method of graphene oxide (GO) adsorbing followed by H2 reducing is developed to prepare reduced graphene oxide (rGO) coating on the 316 L stainless steel bipolar plate. Benefiting from the good ion diffusion inhibition property of rGO nanosheets, the corrosion current density at the PEMFC cathodic working potential for the rGO coated 316 L is 0.115 mu A cm 2, which is over 50 times lower than that for bare 316 L stainless steel (9.71 mu A cm 2). After 24 h potentiostatic tests, rGO coated 316 L is able to maintain its high corrosion resistance (0.155 mu A cm 2). GO adsorbing-H2 reducing is an effective approach to improving the corrosion resistance of 316 L stainless steel bipolar plate for PEMFC.