• 文献标题:   Bicontinuous nanotubular graphene-polypyrrole hybrid for high performance flexible supercapacitors
  • 文献类型:   Article
  • 作  者:   KASHANI H, CHEN LY, ITO Y, HAN JH, HIRATA A, CHEN MW
  • 作者关键词:   nanoporous graphene, polypyrrole, supercapacitor, nanoporous metal
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   71
  • DOI:   10.1016/j.nanoen.2015.11.029
  • 出版年:   2016

▎ 摘  要

Conductive polymers, particularly polypyrrole (PPy), are emerging as promising electrode materials for flexible supercapacitors because of their high pseudocapacitance, low density, high mechanical flexibility and low material costs. However, the practical implementations of PPy based supercapacitors have been prevented by the poor charge/discharge rate capability and low cycle stability. In this study we report a novel three dimensional interconnected nanotubular graphene-PPy (nt-GPPy) hybrid by incorporating PPy into highly conductive and stable nanoporous graphene. The bicontinuous nanotubular hybrid material with a large specific surface area and high conductivity demonstrates significant enhancement in supercapacitance performance of PPy in terms of high specific capacitance, excellent cycling stability and high rate capability. (C) 2015 Elsevier Ltd. All rights reserved.