• 文献标题:   Cobalt oxide nanoparticles anchored on discharged-graphene film for lithium-ion battery
  • 文献类型:   Article
  • 作  者:   FANG D, JI YS, SUN BS, BAO R, YI JH, LUO ZP
  • 作者关键词:   discharge, lithiumion battery, graphene, cobalt oxide
  • 出版物名称:   SOLID STATE IONICS
  • ISSN:   0167-2738 EI 1872-7689
  • 通讯作者地址:   Kunming Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1016/j.ssi.2019.115006
  • 出版年:   2019

▎ 摘  要

In order to improve lithium storage capacity and cycle stability of the electrode materials, the combination of the active material and graphene is an effective way. Reduced graphene oxide (rGO) film on Ti substrate is obtained in an aqueous graphene oxide solution using a two-electrode constant voltage electrodeposition system. Then the rGO film on Ti substrate is used as working electrode to assemble lithium-ion batteries and discharged to 0.01 V. The discharged rGO film further reacts with cobalt ions in the cobalt acetate aqueous solution to fabricate the cobalt oxide (CoO)/rGO-precursor, and subsequently the CoO/rGO-700 composite is obtained by calcining the precursor at 700 degrees C under N-2. Different measurements are conducted to evaluate the samples. The CoO/rGO-700 composites are further used as electrode material of lithium-ion batteries, which deliver an initial capacity of 1290.6 mAh.g(-1) at 100 mA.g(-1). For the first time, the synthetic method reported in this work can be extended to the synthesis of other metal or oxide/rGO composites.