• 文献标题:   Enhanced field emission properties from graphene-TiO2/DLC nanocomposite films prepared by ultraviolet-light assisted electrochemical deposition
  • 文献类型:   Article
  • 作  者:   JIANG JL, DU JF, WANG Q, ZHANG X, ZHU WJ, LI RS, YANG H
  • 作者关键词:   graphene, tio2, diamondlike carbon film, electrochemical deposition, ultraviolet light, field emission
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Lanzhou Univ Technol
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2016.06.084
  • 出版年:   2016

▎ 摘  要

The graphene-TiO2/diamond-like carbon (G-TiO2/DLC) nanocomposite films were prepared on silicon substrates by a simple ultraviolet (UV) light assisted electrochemical deposition process using N, N-dimethylformamide (DMF) as carbon source and TiO2 nanoparticles/graphene sheets as incorporated reagents. The results show that the TiO2 and graphene sheets are uniformly dispersed into the DLC matrix. The UV-light illumination not only affects the morphology of the films, but also promotes the field emission properties, probably due to the effect of photoinduced electron-hole pairs produced from TiO2. The G-TiO2/DLC film exhibits the lowestturn-on field of 5.2 V/mu m and the highest current density of 2950 mu A/cm(2) at the electric field of 8.2 V/mu m. This enhancement of field emission properties are investigated based on the surface morphology of the self-assembled nanostructures, the improved conductivity, together with the reduced work function. (C) 2016 Elsevier B.V. All rights reserved.