• 文献标题:   Defect-Detriment to Graphene Strength Is Concealed by Local Probe: The Topological and Geometrical Effects
  • 文献类型:   Article
  • 作  者:   SONG ZG, ARTYUKHOV VI, WU J, YAKOBSON BI, XU ZP
  • 作者关键词:   graphene, nanoindentation, mechanical propertie, material strength, topological effect, geometrical effect
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Rice Univ
  • 被引频次:   36
  • DOI:   10.1021/nn505510r
  • 出版年:   2015

▎ 摘  要

Defects in solids commonly limit mechanical performance of materials by reducing their rigidity and strength. However, topological defects also induce a prominent geometrical effect in addition to local stress buildup, which is especially pronounced in two-dimensional crystals. These dual roles of defects modulate mechanical responses of the material under local and global probes in very different ways. We demonstrate through atomistic simulations and theoretical analysis that local response of two-dimensional crystals can even be stiffened and strengthened by topological defects as the structure under indentation features a positive Gaussian curvature, while softened and weakened mechanical responses are measured at locations with negative Gaussian curvatures. These findings shed lights on mechanical characterization of two-dimensional materials in general. The geometrical effect of topological defects also adds a new dimension to material design, in the scenario of geometrical and topological engineering.