• 文献标题:   Magnetically separable functionalized graphene oxide decorated with magnetic cyclodextrin as an excellent adsorbent for dye removal
  • 文献类型:   Article
  • 作  者:   LI LL, FAN LL, DUAN HM, WANG XJ, LUO CN
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   24
  • DOI:   10.1039/c4ra06292b
  • 出版年:   2014

▎ 摘  要

Magnetic cyclodextrin/graphene oxide (MCGO) materials were fabricated through a facile chemical route and their application as excellent adsorbents for methylene blue (MB) was also demonstrated. The results from FTIR, SEM, TEM, VSM and XRD showed that MCGO was prepared. The large saturation magnetization (51.13 emu g(-1)) of the synthesized nanoparticles allows fast separation of the MCGO from liquid suspension. The MCGO demonstrate extremely fast MB-removal from wastewater with a high removal efficiency within 50 min. The adsorption kinetics, isotherms and thermodynamics were investigated and indicate that the kinetics and equilibrium adsorption are well-described by pseudosecond- order kinetics and the Langmuir isotherm model, respectively. The results showed that, benefiting from the surface properties of graphene oxide, the hydrophobicity of cyclodextrin, and from the magnetic properties of Fe3O4, the adsorbent possesses quite a good and versatile adsorption capacity towards the dye under investigation. Most importantly, the adsorbent can be easily and efficiently regenerated for reuse with hardly any compromise of the adsorption capacity. The inherent advantages of the nano-structured adsorbent, such as high adsorption capacity, easy operation, rapid extraction, and regeneration, may pave a new, efficient and sustainable way towards highly-efficient dye pollutant removal in water and wastewater treatment.