• 文献标题:   Preparation and electrochemical properties of sodium-reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   CISZEWSKI M, MIANOWSKI A, NAWRAT G
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522
  • 通讯作者地址:   Silesian Tech Univ
  • 被引频次:   9
  • DOI:   10.1007/s10854-013-1259-2
  • 出版年:   2013

▎ 摘  要

Graphite oxide reduction is probably one of the best technique used to obtain large quantities of few-layer graphene. We developed a new method to produce reduced graphene oxide by using sodium metal as a reducing agent with subsequent dehydration in concentrated sulfuric acid. The resulting product was characterized using various analytical techniques with respect to the oxygen content and species of the residual oxygen-containing groups. The reduced graphene oxide prepared by this method was electrochemically tested as electrode in supercapacitors using two-electrode symmetric system and aqueous electrolyte. The product exhibits improved capacitance during cyclic voltammetry measurements. In comparison to parent graphite oxide specific capacity increased from 0.88 to 28 F/g after 10 cycles at scan rate 20 mV/s and dropped to 19.44 F/g after 100 cycles while at scan rate 5 mV/s specific capacity 46.41 F/g was recorded after first cycle and 39.90 F/g after 50 cycles.