• 文献标题:   Electrically powered repeatable air explosions using microtubular graphene assemblies
  • 文献类型:   Article
  • 作  者:   SCHUTT F, RASCH F, DEKA N, REIMERS A, SAURE LM, KAPS S, RANK J, CARSTENSEN J, MISHRA YK, MISSERONI D, VAZQUEZ AR, LOHE MR, NIA AS, PUGNO NM, FENG XL, ADELUNG R
  • 作者关键词:  
  • 出版物名称:   MATERIALS TODAY
  • ISSN:   1369-7021 EI 1873-4103
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.mattod.2021.03.010 EA OCT 2021
  • 出版年:   2021

▎ 摘  要

Controllable rapid expansion and activation of gases is important for a variety of applications, including combustion engines, thrusters, actuators, catalysis, and sensors. Typically, the activation of macroscopic gas volumes is based on ultra-fast chemical reactions, which require fuel and are irreversible. An "electrically powered explosion", i.e., the rapid increase in temperature of a macroscopic relevant gas volume induced by an electrical power pulse, is a feasible repeatable and clean alternative, providing adaptable non-chemical power on demand. Till now, the fundamental problem was to find an efficient transducer material that converts electrical energy into an immediate temperature increase of a sufficient gas volume. To overcome these limitations, we developed electrically powered repeatable air explosions (EPRAE) based on free-standing graphene layers of nanoscale thickness in the form of microtubes that are interconnected to a macroscopic framework. These low-density and highly permeable graphene foams are characterized by heat capacities comparable to air. The EPRAE process facilitates cyclic heating of cm(3)-sized air volumes to several 100 degrees C for more than 100,000 cycles, heating rates beyond 300,000 K s(-1) and repetition rates of several Hz. It enables pneumatic actuators with the highest observed output power densities (>40 kW kg(-1)) and strains similar to 100%, as well as tunable microfluidic pumps, gas flowmeters, thermophones, and micro-thrusters.