• 文献标题:   Electrochemical Properties of Poly(Anthraquinonyl Sulfide)/Graphene Sheets Composites as Electrode Materials for Electrochemical Capacitors
  • 文献类型:   Article
  • 作  者:   LEE W, SUZUKI S, MIYAYAMA M
  • 作者关键词:   poly anthraquinonyl sulfide, graphene, composite, electrochemical capacitor
  • 出版物名称:   NANOMATERIALS
  • ISSN:   2079-4991
  • 通讯作者地址:   Univ Tokyo
  • 被引频次:   14
  • DOI:   10.3390/nano4030599
  • 出版年:   2014

▎ 摘  要

Poly(anthraquinonyl sulfide) (PAQS)/graphene sheets (GSs) composite was synthesized through in situ polymerization to evaluate its performance as an electrode material for electrochemical capacitors. PAQS was successfully synthesized in the presence of GSs with uniform distribution. PAQS/GSs showed a pair of reversible redox peaks at around 0 V (vs. Ag/AgCl). The specific capacitance of PAQS/GSs was 349 F.g(-1) (86 mAh.g(-1)) at a current density of 500 mA.g(-1), and a capacitance of 305 F.g(-1) was maintained even at a high current density of 5000 mA.g(-1). The in situ polymerization of PAQS with GSs facilitated their interaction and enabled faster charge transfer and redox reaction, resulting in enhanced electrode properties.