• 文献标题:   Application of Graphene Oxide-MnFe2O4 Magnetic Nanohybrids as Magnetically Separable Adsorbent for Highly Efficient Removal of Arsenic from Water
  • 文献类型:   Article
  • 作  者:   HUONG PTL, HUY LT, PHAN VN, HUY TQ, NAM MH, LAM VD, LE AT
  • 作者关键词:   adsorption isotherm, mnfe2o4go magnetic nanohybrid, adsorbent, arsenic removal
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Hanoi Univ Sci Technol
  • 被引频次:   10
  • DOI:   10.1007/s11664-015-4314-3
  • 出版年:   2016

▎ 摘  要

In this work, a functional magnetic nanohybrid consisting of manganese ferrite magnetic nanoparticles (MnFe2O4) deposited onto graphene oxide (GO) nanosheets was successfully synthesized using a modified co-precipitation method. The as-prepared GO-MnFe2O4 magnetic nanohybrids were characterized using x-ray diffraction, transmission electron microscopy, Fourier transformed infrared spectroscopy, and vibrating sample magnetometer measurements. Adsorption experiments were performed to evaluate the adsorption capacities and efficient removal of arsenic of the nanohybrid and compared with bare MnFe2O4 nanoparticles and GO nanosheets. Our obtained results reveal that the adsorption process of the nanohybrids was well fitted with a pseudo-second-order kinetic equation and a Freundlich isotherm model; the maximum adsorption capacity and removal efficiency of the nanohybrids obtained 240.385 mg/g and 99.9% with a fast response of equilibrium adsorption time 20 min. The larger adsorption capacity and shorter equilibrium time of the GO-MnFe2O4 nanohybrids showed better performance than that of bare MnFe2O4 nanoparticles and GO nanosheets. The advantages of reusability, magnetic separation, high removal efficiency, and quick kinetics make these nanohybrids very promising as low-cost adsorbents for fast and effective removal of arsenic from water.