• 文献标题:   One-step synthesis of CoMoO4/graphene composites with enhanced electrochemical properties for supercapacitors
  • 文献类型:   Article
  • 作  者:   XIA XF, LEI W, HAO QL, WANG WJ, WANG X
  • 作者关键词:   graphene, comoo4, supercapacitor, electrode material, nanocomposite
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   151
  • DOI:   10.1016/j.electacta.2013.03.131
  • 出版年:   2013

▎ 摘  要

A facile hydrothermal method was provided for synthesis of the CoMoO4/graphene (CoMoO4/G) with the enhanced electrochemical properties for supercapacitor. The Co2+ ions were adsorbed on the graphene oxide by electrostatic interaction, followed by adding (NH4)(6)Mo7O24 and adjusting pH. The CoMoO4 nanoparticles were grown on the graphene sheet after hydrothermal reaction. The as-prepared CoMoO4/G composites possessed high surface/body ratios and large electroactive regions, which could facilitate easy accession of OH- ions and fast charge transport. As a result, CoMoO4/G composites achieved a specific capacitance about 394.5 F g(-1) and a specific energy density around 54.8 Wh kg(-1) calculated from the CV curve at 1 mV s(-1), which was higher than that of pure-CoMoO4 (72.0 F g(-1), 10.0 Wh Kg(-1)). Moreover, in comparison with pure-CoMoO4, the CoMoO4/G composites exhibited low electrochemical resistance, good rate capability and well cycle life. (C) 2013 Elsevier Ltd. All rights reserved.