• 文献标题:   Ultrathin Titanate Nanosheets/Graphene Films Derived from Confined Transformation for Excellent Na/K Ion Storage
  • 文献类型:   Article
  • 作  者:   ZENG C, XIE FX, YANG XF, JARONIEC M, ZHANG L, QIAO SZ
  • 作者关键词:   anode material, sandwich structure, sodium titanate, sodiumion batterie, ultrathin nanosheet
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   South China Univ Technol
  • 被引频次:   36
  • DOI:   10.1002/anie.201803511
  • 出版年:   2018

▎ 摘  要

Confined transformation of assembled two-dimensional MXene (titanium carbide) and reduced graphene oxide (rGO) nanosheets was employed to prepare the free-standing films of the integrated ultrathin sodium titanate (NTO)/potassium titanate (KTO) nanosheets sandwiched between graphene layers. The ultrathin Ti-based nanosheets reduce the diffusion distance while rGO layers enhance conductivity. Incorporation of graphene into the titanate films produced efficient binder-free anodes for ion storage. The resulting flexible NTO/rGO and KTO/rGO electrodes exhibited excellent rate performances and long cycling stability characterized by reversible capacities of 72mAhg(-1) at 5Ag(-1) after 10000 cycles and 75mAhg(-1) after 700 cycles at 2Ag(-1) for sodium and potassium ion batteries, respectively. These results demonstrate the superiority of the unique sandwich-type electrodes.