• 文献标题:   Noble-Metal-Free Ni(OH)(2)-Modified CdS/Reduced Graphene Oxide Nanocomposite with Enhanced Photocatalytic Activity for Hydrogen Production under Visible Light Irradiation
  • 文献类型:   Article
  • 作  者:   YAN ZP, YU XX, HAN A, XU P, DU PW
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   82
  • DOI:   10.1021/jp5065402
  • 出版年:   2014

▎ 摘  要

A series of nickel hydroxide modified cadmium sulfide/reduced graphene oxide (Ni(OH)(2)-CdS/rGO) nanocomposites were synthesized and characterized. The photocatalytic activity of the as-prepared Ni(OH)(2)-CdS/rGO materials for hydrogen production from water under visible light irradiation (lambda > 420 nm) was investigated. The results demonstrated that Ni(OH)(2) is an efficient cocatalyst for photocatalytic hydrogen production and rGO can significantly enhance the rate of photocatalysis. The optimal Ni(OH)(2) loading was found to be 1.0 wt %, giving a rate for hydrogen production of 4731 mu mol.h(-1).g(-1), which is nearly 10 times higher than that of CdS/rGO photocatalyst under the same condition. This work demonstrated the synergetic effect of Ni(OH)(2) and rGO to enhance catalytic activity for visible light-driven hydrogen production.