• 文献标题:   Gold nanoparticle-decorated graphene oxide: Synthesis and application in oxidation reactions under benign conditions
  • 文献类型:   Article
  • 作  者:   POCKLANOVA R, RATHI AK, GAWANDE MB, DATTA KKR, RANC V, CEPE K, PETR M, VARMA RS, KVITEK L, ZBORIL R
  • 作者关键词:   reduced graphene oxide, gold nanocomposite, recyclable catalyst, oxidation reaction, sustainable protocol, heterogeneous catalysi
  • 出版物名称:   JOURNAL OF MOLECULAR CATALYSIS ACHEMICAL
  • ISSN:   1381-1169 EI 1873-314X
  • 通讯作者地址:   Palacky Univ
  • 被引频次:   30
  • DOI:   10.1016/j.molcata.2016.07.047
  • 出版年:   2016

▎ 摘  要

Gold nanoparticles (similar to 3 nm, 4 wt% Au) dispersed on reduced graphene oxide (Au/rGO) surface were prepared via the reduction of gold (III) chloride using sodium citrate on reduced graphene oxide support. The chemical, morphological, and size analyses of Au/rGO by XRD, XPS, TEM, HR-TEM/EDS, AAS, and Raman spectroscopy revealed that the hybrid material comprised of a well-defined rGO support decorated with gold nanoparticles. The ensuing catalyst was evaluated for the oxidation of ethyl benzenes (yields up to 95%) and oxidative esterification of aldehydes (73-97%) using oxygen as an environmentally friendly oxidant in good to excellent yields; reusable and recyclable catalyst displayed high activity without the use of toxic organic solvents. (C) 2016 Elsevier B.V. All rights reserved.