• 文献标题:   Enhanced functional properties of CeO2 modified graphene/epoxy nanocomposite coating through interface engineering
  • 文献类型:   Article
  • 作  者:   QIAN Y, ZHENG W, CHEN WG, FENG T, LIU TX, FU YQ
  • 作者关键词:   epoxy resin, graphene, ceria, corrosion resistance, conductivity
  • 出版物名称:   SURFACE COATINGS TECHNOLOGY
  • ISSN:   0257-8972 EI 1879-3347
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.surfcoat.2020.126819 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

This paper reports significant enhancement of corrosion resistance and electrical properties of waterborne epoxy coatings through additions of ceria modified graphene. Results showed that ceria particles were uniformly distributed and covalently bonded onto the surface of graphene. A dense interface layer was formed between the ceria modified graphene and epoxy matrix by aliphatic ether bonds. The composite coating with a modified graphene content of 0.5 wt% exhibited the best corrosion resistance with the highest impedance modulus (e.g., 10(3) Omega cm(2) for the damaged coating) and the lowest corrosion rate (e.g., 0.002 mm/year). The excellent corrosion resistance of the composite coating is related to the barrier effect of graphene and the inhibition effect of ceria on metal corrosion. Moreover, the coating showed a low percolation threshold of 0.231 vol% and its electrical conductivity reached 10(-5) S/m when the content of modified graphene was 0.5 wt%.