• 文献标题:   Thermal enhancement of chemical doping in graphene: a Raman spectroscopy study
  • 文献类型:   Article
  • 作  者:   MALARD LM, MOREIRA RL, ELIAS DC, PLENTZ F, ALVES ES, PIMENTA MA
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICSCONDENSED MATTER
  • ISSN:   0953-8984 EI 1361-648X
  • 通讯作者地址:   Univ Fed Minas Gerais
  • 被引频次:   34
  • DOI:   10.1088/0953-8984/22/33/334202
  • 出版年:   2010

▎ 摘  要

The Raman spectrum of monolayer graphene deposited on the top of a silicon oxide/silicon substrate was investigated as a function of temperature up to 515 K. An anomalous temperature dependence of the Raman features was observed, including an important frequency upshift for the Raman G band at room temperature, after the heating process. On the other hand, the frequency of the Raman G' band is only slightly affected by the thermal treatment. We discuss our experimental results in terms of doping and strain effects associated with the interaction of graphene with the substrate and with the presence of water in the sample. We conclude that the doping effect gives the most important contribution to the spectral changes observed after the thermal cycle.