• 文献标题:   A novel and simple strategy for simultaneous determination of dopamine, uric acid and ascorbic acid based on the stacked graphene platelet nanofibers/ionic liquids/chitosan modified electrode
  • 文献类型:   Article
  • 作  者:   NIU XL, YANG W, GUO H, REN J, YANG FS, GAO JZ
  • 作者关键词:   graphene nanofiber, ionic liquid, dopamine, uric acid, ascorbic acid, simultaneous determination
  • 出版物名称:   TALANTA
  • ISSN:   0039-9140 EI 1873-3573
  • 通讯作者地址:   NW Normal Univ
  • 被引频次:   59
  • DOI:   10.1016/j.talanta.2012.07.077
  • 出版年:   2012

▎ 摘  要

A promising electrochemical sensor for simultaneous determination of dopamine (DA), uric acid (UA) and ascorbic acid (AA) was fabricated based on the stacked graphene platelet nanofibers (SGNF)/ionic liquid (IL)/chitosan (CS) modified electrode. The SGNF/IL/CS modified electrode possessed excellent electrocatalytic activity towards the oxidation of DA, UA and AA with obvious reduction of overpotential and increased peak current, and the separations of oxidation peak potentials of DA-UA, DA-AA, and UA-AA were of 151, 213 and 364 mV, respectively. Under the optimum conditions, the linear range for the detection of DA, UA and AA were 0.05-240, 0.12-260, and 30-350 mu M with the lowest detection limits of 0.05, 0.10 and 14.8 mu M for DA, UA and AA, respectively. In addition, the electrochemical sensor showed high sensitivity, excellent selectivity, reproducibility and long-term stability. (C) 2012 Elsevier B.V. All rights reserved.