• 文献标题:   Facile synthesis of hybrid MoS2/graphene nanosheets as high-performance anode for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG R, WANG JK, LI C, LIU T, YAO TH, ZHU L, HAN XG, WANG HK
  • 作者关键词:   mos2, graphene, pyrolysi, sodiumion batterie
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   4
  • DOI:   10.1007/s11581-019-03235-7
  • 出版年:   2020

▎ 摘  要

We report the facile synthesis of molybdenum disulfide (MoS2) nanosheets on graphene nanosheets (MoS2@GNSs) via simple thermal decomposition of ammonium tetrathiomolybdate in Ar-H-2 atmosphere. When used as anode materials for sodium-ion batteries (SIBs), the as-prepared MoS2@GNSs electrode delivers reversible capacities of 389 and 383 mA h g(-1) at current densities of 200 mA g(-1) and 500 mA g(-1) after 200 cycles, respectively, which is much higher than that of the MoS2 electrode (253 mA h g(-1) after 171 cycles at 200 mA g(-1)). The superior sodium storage performance of MoS2@GNSs including excellent cycle stability and rate performance can be attributed to the introduction of graphene materials, which not only buffer the volume changes of MoS2 upon sodiation/desodiation but also improve the electrical conductivity.