• 文献标题:   Covalently bonded boron nitride quantum dot and reduced graphene oxide composite electrode for highly efficient supercapacitors
  • 文献类型:   Article
  • 作  者:   LEE JW, KSHETRI T, PARK KR, KIM NH, PARK OK, LEE JH
  • 作者关键词:   boron nitride quantum dot, reduced graphene oxide, hybridnanostructure, electrical propertie, interface, interphase, surface treatment
  • 出版物名称:   COMPOSITES PART BENGINEERING
  • ISSN:   1359-8368 EI 1879-1069
  • 通讯作者地址:  
  • 被引频次:   14
  • DOI:   10.1016/j.compositesb.2021.109089 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

This study investigates the synthesis and application of boron nitride quantum dot (BNQD) covalently bonded reduced graphene oxide (rGO) hybrid materials as a novel electrode material for supercapacitors. Because of the p-doping as well as the enhanced hydrophilicity and interfacial bonding force enabled by the hybridization of amine-functionalized boron nitride quantum dot (A-BNQD) with rGO via the chemical coupling reaction, the ABNQD/rGO shows improved charge carrier density, wettability of electrolyte, and durability. As a result of the synergistic effects, the A-BNQD/rGO as a supercapacitor electrode shows much higher specific capacitance compared to those of rGO and raw BNQD/rGO at a current density of 1 A g-1. Further, the A-BNQD/rGO shows high cycling stability, maintaining almost 94.38%, even after 10,000 cycles due to the enhanced interfacial bonding force between the A-BNQD and rGO. Besides, the fabricated symmetric supercapacitor exhibits high specific capacitance (90 F g- 1@1 A g-1), an energy density (12.5 Wh kg-1@0.5 kW kg- 1), and good cycling stability. This result suggested that the fabricated A-BNQD/rGO has great potential as electrode materials for high-performance supercapacitors.