• 文献标题:   Short duration growth of high-quality multi-layered graphene by temperature-controlled rapid heating chemical vapor deposition
  • 文献类型:   Article
  • 作  者:   KITANO A, TANAKA M, KUBO T, SHIMIZU T
  • 作者关键词:   graphene, chemical vapor deposition, materials engineering, surface treatment
  • 出版物名称:   JAPANESE JOURNAL OF APPLIED PHYSICS
  • ISSN:   0021-4922 EI 1347-4065
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.35848/1347-4065/ac89c0
  • 出版年:   2022

▎ 摘  要

Chemical vapor deposition using a rapid thermal annealing (RTA) system at atmospheric pressure with diluted methane gas (0.48 vol%)/Ar enabled the growth of high-quality multi-layered graphene on a Cu substrate at 1000 degrees C within a short time span. The minimum temperature rise time (including the reduction time) and growth time were 300 and 90 s, respectively. These conditions gave graphene films exhibiting 98.6% substrate coverage. The lateral sizes of the resulting graphene domains ranged from 0.2 to 1.2 mu m with an average size of 0.46 mu m while the film thicknesses were estimated to range from two to several layers based on the Raman 2D/G peak ratios. The Raman D peak indicative of defects was not detected on the graphene films. Precise control of the growth temperature within the range of 900 degrees C-1000 degrees C promoted reduction reactions and improved the quality of the graphene.