• 文献标题:   The role of graphene oxide anchored 1-amino-2-naphthol-4-sulphonic acid on the adsorption of uranyl ions from aqueous solution: kinetic and thermodynamic features
  • 文献类型:   Article
  • 作  者:   GADO M, ATIA B, MORCY A
  • 作者关键词:   adsorption, uranium vi, graphene oxide, 1amino2naphthol4sulphonic acid
  • 出版物名称:   INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • ISSN:   0306-7319 EI 1029-0397
  • 通讯作者地址:   Nucl Mat Author
  • 被引频次:   5
  • DOI:   10.1080/03067319.2019.1617283 EA MAY 2019
  • 出版年:   2019

▎ 摘  要

Graphene oxide-1-amino-2-naphthol-4-sulphonic acid (GOANS) adsorbent synthesised successfully from a natural source (Cattle bones) for the U(VI) ions removal from liquid waste solutions. The synthesised adsorbent characterised via Fourier transform infrared (FTIR) spectroscopy, Brunauer-Emmett-Teller (BET) Surface Area Analysis, Energy-dispersive X-ray spectroscopy(EDX) pattern and scanning electron microscopy (SEM). Various experimental parameters (time, adsorbent weight, initial uranium concentration and temperature) investigated and the results reveal that a higher uptake capacity of 311.5 mg/g achieved at pH 4 within 60 minutes. The obtained findings fitted well with thermodynamic, isothermal (Langmuir and Freundlich model) and pseudo second order kinetics. The negative sign of specified the spontaneity of adsorption process in the thermodynamic study, (endothermic) and positive sign indicate high randomness after adsorption.