• 文献标题:   Laser-Scribed N-Doped Graphene for Integrated Flexible Enzymatic Biofuel Cells
  • 文献类型:   Article
  • 作  者:   KONG XK, GAI PP, GE L, LI F
  • 作者关键词:   enzymatic biofuel cell, flexible device, nitrogendoped, laserscribed graphene, high power output
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Qingdao Agr Univ
  • 被引频次:   0
  • DOI:   10.1021/acssuschemeng.0c03051
  • 出版年:   2020

▎ 摘  要

Flexible enzymatic biofuel cells (EBFCs) have been considered as alternative power sources for wearable devices, in which, the design of the substrate electrode is of significance for its mechanical robustness and performance output. Herein, we developed an integrated flexible EBFC based on N-doped graphene directly obtained with a polyimide film precursor via a simple laser-scribed method. Encouragingly, the laser-scribed N-doped graphene (LSNG) possessed excellent mechanical robustness and conductibility. More importantly, the LSNG electrode exhibited excellent electrocatalysis performance, which can remarkably reduce the overpotential of the cofactor enzyme. With glucose and O-2 as fuels, the integrated flexible EBFC could produce a maximum power density (P-max) to 27 +/- 1.7 mu W cm(-2) at open-circuit voltages (E-OCV) of 0.45 +/- 0.03 V, being superior or comparable to those of the reported flexible EBFC. In addition, the E-OCV of the device retained 78% of its initial value even after storage for 20 days and it showed almost no change after bending 100 times. Overall, the LSNG was an appealing alternative candidate to construct integrated biofuel cells and other flexible devices.