• 文献标题:   Adsorption of Co(II) on Graphene Oxides from Aqueous Solution
  • 文献类型:   Article
  • 作  者:   ZHU H, XU XT, ZHONG X
  • 作者关键词:   graphene oxide, adsorption, co ii, humic acid
  • 出版物名称:   POLISH JOURNAL OF ENVIRONMENTAL STUDIES
  • ISSN:   1230-1485 EI 2083-5906
  • 通讯作者地址:   Sichuan Univ Arts Sci
  • 被引频次:   3
  • DOI:   10.15244/pjoes/63730
  • 出版年:   2016

▎ 摘  要

Graphene oxide (GO) was synthesized and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), and Fourier transformed infrared spectra (FT-IR). The adsorption of Co(II) on GO was studied as a function of contact time, pH, ionic strength, humic acid, Co(II) concentration, and temperature. The adsorption of Co(II) is strongly dependent on the pH values and weakly dependent on ionic strength. The adsorption thermodynamics of Co(II) on GO was carried out at 303, 313, and 333 K to obtain the corresponding thermodynamic data (Delta H-0, Delta S-0, and Delta G(0)), which suggested that the adsorption of Co(II) on GO is a spontaneous and endothermic process. GO provided a promising candidate for the preconcentration and solidification of Co(II) from large volumes of aqueous solutions.