• 文献标题:   Synthesis and electrochemical performance of a spherical flower-like MoS2 /graphene anode material for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   MOU YP, WANG C, ZHAN L, LIU X, WANG YL
  • 作者关键词:   mos2, graphene, anode material, lithiumion battery
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827
  • 通讯作者地址:   East China Univ Sci Technol
  • 被引频次:   1
  • DOI:  
  • 出版年:   2016

▎ 摘  要

A MoS2/graphene composite was synthesized at 240 degrees C by a hydrothermal method using graphene oxide, Na2MoO4 and CS (NH2)(2) as the raw materials. Results indicate that the spherical flower-like MoS2 structure was self-assembled by thin MoS2 micrometer size layers and dispersed uniformly on the surface of graphene. The MoS2/graphene composite as an anode material retains a capacity of 735. 2 mAli/g after 100 cycles under a current density of 100 mA/g and has a good rate performance (490.3 mAh/g at 400 mA/g and 411.9 mAh/g at 800 mA/g). The excellent electrochemical performance of the composite is attributed to its special structure. The thin MoS2, layers shorten the diffusion and transport paths for Li+ ions and electrons. The abundant mesopores are beneficial for ion diffusion and act as a buffer to inhibit volume changes during charge-discharge. Graphene increases the charge-discharge rate of MoS2 effectively owing to its high conductivity and high surface area.