• 文献标题:   CuMn2O4 anchored on graphene sheets as a high-performance electrodes for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   CHANDRAN MKN, BABU GNS, SATHISH M
  • 作者关键词:   graphene, anode, sodium ion battery, rate capability, transition metal oxide
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.est.2023.107346 EA APR 2023
  • 出版年:   2023

▎ 摘  要

A novel class of CuMn2O4 (CMO) nanoparticles were synthesized by the reflux route method and explored as an anode in sodium-ion batteries. This work deals with the homogenous distribution of CuMn2O4 (CMO) nano -particles interconnected within the graphene sheet. HR-TEM deceptively evidences the homogeneous distribu-tion and well-defined CuMn2O4 nanoparticles over graphene sheets (CMO/G). This appropriately designed architecture of CMO/G allows adequate void space to assimilate the substantial volume fluctuation during cycling, improve reaction sites, and enhance electron transport, resulting in significant electrochemical perfor-mance as an anode in sodium-ion batteries. The CMO/G anode showed a high capacity of 313 mAh g-1 at 100 mA g-1 with 70 % capacity retention after 50 cycles, and under the high current of 2 A g-1, it exhibits as high as 145 mAh g-1. Moreover, the title anode is capable of delivering stable appreciable capacity of 164 mAh g-1 for extended 300 cycles at 1 A g-1. CMO/G composite anode has been validated as a high-efficient anode for sodium -ion battery applications in this study.