• 文献标题:   Fabrication of graphene/azobenzene-perylene diimide derivative modified electrochemical sensors for the dopamine detection based on full factorial experimental design
  • 文献类型:   Article
  • 作  者:   VAROL TO, PERK B, AVCI O, AKPOLAT O, HAKLI O, XUE CM, LI Q, ANIK U
  • 作者关键词:   dopamine, graphene, perylene diimide, full factorial design, experimental design
  • 出版物名称:   MEASUREMENT
  • ISSN:   0263-2241 EI 1873-412X
  • 通讯作者地址:   Mugla Sitki Kocman Univ
  • 被引频次:   3
  • DOI:   10.1016/j.measurement.2019.106867
  • 出版年:   2019

▎ 摘  要

In this study, carbon paste electrode (CPE) was modified with graphene and a novel azobenzene-perylene diimide derivative (P4SAc) and utilized for the dopamine detection. Electrochemical performances of modified electrochemical platforms were examined and graphene/P4SAc/CPE exhibited the highest increment in dopamine oxidation signal. Experimental parameters were optimized by using full factorial design and analytical characteristics were examined. As a result, a linear range was obtained in the concentration range of 5-100 mu M with a detection limit of 0.26 mu M (n = 3). The developed sensor was also applied for the dopamine detection in injection samples and very promising results were obtained. (C) 2019 Elsevier Ltd. All rights reserved.