• 文献标题:   Enhanced capacity and significant rate capability of Mn3O4/reduced graphene oxide nanocomposite as high performance anode material in lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   WENG SC, BRAHMA S, HUANG PC, HUANG YC, LEE YH, CHANG CC, HUANG JL
  • 作者关键词:   li ion batterie, mn3o4/rgo nanocomposite, anode material, chemical synthesi, energy storage
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Natl Cheng Kung Univ
  • 被引频次:   2
  • DOI:   10.1016/j.apsusc.2019.144629
  • 出版年:   2020

▎ 摘  要

We report enhanced capacity, significant rate capability of Mn3O4 microsheet and reduced graphene oxide (Mn3O4/rGO) nanocomposite as high performance anode material in lithium ion battery. The Mn3O4/rGO nanocomposite prepared by a facile, low temperature chemical reduction procedure has achieved superior capacity of similar to 677 mAh g(-1) (current rate = 123 mA g(-1)) after 150 charge/discharge cycles (retention = 85%) and appreciable rate capability of 640 mAh g(-1) @1.2 A g(-1). The comparative investigation reveals the distinguished electrochemical performance of Mn3O4/rGO as compared with MnO2/rGO, MnO2 and graphene oxide. Lithium ion diffusion coefficient of Mn3O4/rGO (2.4 x 10(-1) m(2) s(-1)) is higher than MnO2/rGO, MnO2 and graphene oxide that facilitates the smooth passage of Li ions in the composite delivering noticeable electrochemical performance. Mn3O4/rGO is synthesized by the simple chemical reduction of MnO2 nanorod/rGO nanocomposite and the procedure can be extended for the synthesis of other potentially useful, simple/complex metal oxides (varying shape and size) as anode materials in lithium ion batteries.