• 文献标题:   Adsorption kinetics and isotherms study of 2,4-dichlorophenoxyacetic acid by 3dimensional/graphene oxide/magnetic from aquatic solutions
  • 文献类型:   Article, Early Access
  • 作  者:   HAJIGHASEMKHAN A, TAGHAVI L, MONIRI E, HASSANI AH, PANAHI HA
  • 作者关键词:   2dichlorophenoxyacetic acid, polymer nanomagnetic adsorbent, thermosensitive adsorbent, adsorption
  • 出版物名称:   INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • ISSN:   0306-7319 EI 1029-0397
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   1
  • DOI:   10.1080/03067319.2020.1734194 EA MAR 2020
  • 出版年:  

▎ 摘  要

3D polymer nanomagnetic (3D/GO/Fe3O4) adsorbent was fabricated and used for determining removal of 2,4-D from an aqueous solution. The adsorbent was characterised by FTIR, XRD, FE-SEM, TEM, VSM, and TGA. The influence of pH, contact time, 2,4-D initial concentration, temperature and adsorbent dosage in adsorption efficiency was examined. Maximum removal (100%) was observed at the optimum adsorption condition (pH: 3, contact time: 180 min, adsorbent dosage: 5 g/L, and temperature: 50 degrees C). Moreover, the equilibrium adsorption data were fitted to Langmuir (R-2 = 0.995) and pseudo-second-order model (R-2 = 0.991). The model parameters were evaluated and maximum adsorption capacity (q(max) = 5.62 mg/g) was reported. In addition, applying adsorbent to remove 2,4-D from the real samples of agricultural wastewater shows successfully 100% removal efficiency. Therefore, according to removal efficiency (100%), this adsorbent is an excellent alternative for removal herbicide in high temperature industry.