• 文献标题:   Synthesis of Graphene Quantum Dots Decorated With Se, Eu and Ag As Photosensitizer and Study of Their Potential to Use in Photodynamic Therapy
  • 文献类型:   Article
  • 作  者:   ROEINFARD M, ZAHEDIFAR M, DARROUDI M, ZAK AK, SADEGHI E
  • 作者关键词:   graphene quantum dot, photoluminescence, afterglow, polyethylene glycol, photodynamic therapy
  • 出版物名称:   JOURNAL OF FLUORESCENCE
  • ISSN:   1053-0509 EI 1573-4994
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1007/s10895-020-02674-0 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

GQDs decorated with europium (Eu), silver (Ag) and selenium (Se) at molar ratios of 0.1%, 0.3% and 0.5% were produced for the first time at different temperatures of 180 degrees C, 200 degrees C and 220 degrees C. Surface passivation was carried out with polyethylene glycol (PEG) to increase the intensity of photoluminescence (PL) of the produced samples. The prepared quantum dots were characterized by X-Ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR), transmission electron microscopy (TEM), PL and ultraviolet-visible spectroscopy. GQDs synthesized at 180 degrees C and decorated with Se (0.3%) had maximum PL intensity along with long lasted afterglow over 90 min compared with other samples. Excitation wavelength at 360 nm produced maximum emission at 600-900 nm and resulted in high singlet oxygen (O-1 (2)) generation which makes it a good candidate for photodynamic therapy applications.