• 文献标题:   Rapid electrochemical detection of ferulic acid based on a graphene modified glass carbon electrode
  • 文献类型:   Article
  • 作  者:   ZHANG YL, LIU YP, YANG ZM, YANG YC, PANG PF, GAO YT, HU QF
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL METHODS
  • ISSN:   1759-9660
  • 通讯作者地址:   Yunnan Univ Nationalities
  • 被引频次:   8
  • DOI:   10.1039/c3ay40084k
  • 出版年:   2013

▎ 摘  要

A graphene nanosheet modified glassy carbon electrode (GN/GCE) is proposed as a voltammetric sensor for ferulic acid with good sensitivity, selectivity and reproducibility. The sensor oxidizes ferulic acid in a surface-confined and quasi-reversible process, as revealed by cyclic voltammetry. The results show more favorable electron transfer kinetics than for a bare glassy carbon electrode (GCE). The linear response of the sensor is from 5 x 10(-7) to 5 x 10(-5) M with a detection limit of 2 x 10(-7) M (S/N = 3). Graphene, as a single nanosheet, shows more favorable electrochemical activity and should be a more robust and advanced carbon electrode material, which provides a promising platform for electrochemical sensors and biosensors. The method was successfully applied to the detection of ferulic acid in pharmaceutical tablets with satisfactory results.