• 文献标题:   Graphene oxide framework-confined Ru (Ru@GOF) as recyclable catalyst for hydrogenation of levulinic acid into gamma-valerolactone with formic acid
  • 文献类型:   Article
  • 作  者:   SEENIVASAN K, TRAN TPN, MOHAN P, TON NNT, THAKUR A, CHAMMINGKWAN P, RAWAT DS, TANIIKE T
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s10853-022-07340-3 EA JUN 2022
  • 出版年:   2022

▎ 摘  要

Novel Ru-based heterogeneous catalysts are reported, where Ru nanoparticles are confined in the gallery space of graphene oxide frameworks (GOFs) pillared with organic linkers. These catalysts were then studied for the conversion of levulinic acid into gamma-valerolactone using formic acid as a hydrogen source. The activity and recyclability of the Ru@GOF catalysts were found to be excellent compared to those of an unconfined Ru/GO catalyst and catalysts reported in the literature. gamma-Valerolactone was obtained in the yield of 92 mol% with the turnover frequency of 7240 h(-1). A similar yield level was maintained at least up to 5 cycles. [GRAPHICS]