• 文献标题:   Synthesis and Characterization of Nanoparticles, Nanotubes, Nanopans, and Graphene-like Structures of Boron Nitride
  • 文献类型:   Review
  • 作  者:   RAIDONGIA K, GOMATHI A, RAO CNR
  • 作者关键词:   boron nitride, graphene like bn, nanotube, nanoparticle, nanopan, urea route
  • 出版物名称:   ISRAEL JOURNAL OF CHEMISTRY
  • ISSN:   0021-2148 EI 1869-5868
  • 通讯作者地址:   Int Ctr Mat Sci
  • 被引频次:   12
  • DOI:   10.1002/ijch.201000047
  • 出版年:   2010

▎ 摘  要

By heating H3BO3 with urea in 1 6 molar ratio, nanoparticles and nanotubes of BN are obtained The urea-boric acid reaction can also be exploited to obtain graphene analogues of BN, with the number of layers depending on the relative proportions of the two reactants Synthesis with a high proportion of urea yields a product containing graphene analogues of BN with an average of 2 layers The surface area of BN increases with the decreasing number of layers, and the high surface area BN also exhibits high CO2 adsorption Few layer BN can be solubilized by interaction with Lewis bases Nanopans and nanosheets formed by graphene like BN are generated by the vapor phase reaction of NH3 and BBr3 at 1223 K Nanopans of BN, being reported for the first time, have a bottom comprising single layer BN and a wall of 0 7 nm height The average inner volume of the nanopan is around 400 nm(3)