• 文献标题:   Preparation of graphene oxide-montmorillonite nanocomposite and its application in multiple-pollutants removal from aqueous solutions
  • 文献类型:   Article
  • 作  者:   ZHANG CY, LUAN JD, CHEN W, KE X, ZHANG HJ
  • 作者关键词:   crosslinking modification, graphene oxidemontmorillonite nanocomposite, pb2+, pnitrophenol, simultaneous removal
  • 出版物名称:   WATER SCIENCE TECHNOLOGY
  • ISSN:   0273-1223 EI 1996-9732
  • 通讯作者地址:   Shenyang Aerosp Univ
  • 被引频次:   1
  • DOI:   10.2166/wst.2019.046
  • 出版年:   2019

▎ 摘  要

It is of interest to develop a novel fabrication method of a mineral adsorbent for wastewater treatment to remove the combination of heavy metal ions and refractory organic contaminants. The crosslinking agent stearyl trimethyl ammonium chloride was added into a suspension of montmorillonite and graphene oxide to implement their recombination to fabricated graphene oxide-montmorillonite nanocomposite (GMN). The fabricated nanocomposite was characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, Brunauer-Emmett-Teller analysis and zeta potential. Results indicated that GMN exhibited a honeycomb texture, providing the chemical reaction site for the simultaneous adsorption of Pb2+ and p-nitrophenol (PNP). Factors including pH value, contact time, contact temperature and GMN dosage in the adsorption process were crucial for both Pb2+ adsorption and PNP adsorption. The optimum adsorption capacities of Pb2thorn and PNP onto GMN were 19.39 mg.g(-1) and 14.90 mg.g(-1) under the condition of pH = 6, contact temperature 55 degrees C, contact time 60 min and GMN dosage 0.10 g, respectively. Data from experimental studies on simultaneous adsorption was well described by the pseudo-second-order model. The implementation of this work shows that GMN is a promising material for application in the simultaneous removal of heavy metal ions and refractory organic contaminants.