• 文献标题:   The modeling evidences for Th(IV) sorption on graphene oxide
  • 文献类型:   Article
  • 作  者:   YE F, TANG YN
  • 作者关键词:   radionuclide, sorption, surface complexation modeling, graphene oxide
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   Shaoxing Univ
  • 被引频次:   1
  • DOI:   10.1007/s10967-016-4855-9
  • 出版年:   2016

▎ 摘  要

The effect of environmental factors on Th(IV) sorption on graphene oxide (GO) was elucidated by batch techniques. The characteristic results revealed that GO displayed a variety of oxygenated functional groups. The sorption of Th(IV) on GO was independent of ionic strength, suggesting the inner-sphere surface complexation. The maximum sorption capacity of Th(IV) on GO at pH 3.0 and 293 K was 54.74 mg/g. The thermodynamic parameters showed that the Th(IV) sorption on GO was an exothermal and spontaneous processes. The sorption of Th(IV) on GO can be fitted satisfactorily by diffuse layer model with SOTh3+ and species.