• 文献标题:   A simple and controllable nanostructure comprising non-conductive poly(vinylidene fluoride) and graphene nanosheets for supercapacitor
  • 文献类型:   Article
  • 作  者:   SUN J, HE LH, ZHAO QL, CAI LF, SONG R, HAO YM, MA Z, HUANG W
  • 作者关键词:   reduced graphene oxide rgo, poly vinylidene fluoride pvdf, nanocomposite, supercapacitor
  • 出版物名称:   FRONTIERS OF MATERIALS SCIENCE
  • ISSN:   2095-025X EI 2095-0268
  • 通讯作者地址:   Zhengzhou Univ Light Ind
  • 被引频次:   3
  • DOI:   10.1007/s11706-012-0163-7
  • 出版年:   2012

▎ 摘  要

An effective method was used to produce stable and homogeneous colloidal suspensions of highly reduced graphene oxide (RGO) in N, N-dimethylformamide (DMF) without the assistance of dispersing agents. According to the results of general characterization, relatively pure graphene sheets with the morphology of single layer or few-layer structure were obtained. Then nanocomposite powders of RGO and poly (vinylidene fluoride) (PVDF) were prepared by vacuum filtration of the mixed dispersions of both components. The nanocomposites exhibit a high-frequency capacitative response with small equivalent series resistance (ESR) at 0.4 Omega, a nearly rectangular cyclic voltammogram and possess a rapid current response as electrodes for super-capacitor in 5 mol/L KOH electrolyte. Furthermore, after 600 galvanostatic charge/discharge cycles, the supercapacitor still performs a very high stability and efficiency of capacitance.