• 文献标题:   The spectrochemical behavior of composites based on poly (para-phenylenevinylene), reduced graphene oxide and pyrene
  • 文献类型:   Article
  • 作  者:   ILIE M, BAIBARAC M
  • 作者关键词:   polymers functionalization, composite, conducting polymer, infrared spectroscopy, uvvis spectroscopy
  • 出版物名称:   OPTICAL MATERIALS
  • ISSN:   0925-3467 EI 1873-1252
  • 通讯作者地址:   Natl Inst Mat Phys
  • 被引频次:   1
  • DOI:   10.1016/j.optmat.2017.06.002
  • 出版年:   2017

▎ 摘  要

A new composite material based on poly (para-phenylenevinylene) (PPV), pyrene (Py) and reduced graphene oxide (RGO) is synthesized using thermal conversion route. The properties of this material are investigated by Raman scattering, photoluminescence (PL), infrared (IR) and ultraviolet visible (UV-Vis) spectroscopy. Adding Py at PPV precursor solution (PPV PS) containing RGO, yields to important modifications in both vibrational and electronic properties of these composites. The presence of Py into PPV matrix determines a blue shift of PPV PL. According to Raman and IR studies, PPV is non-covalently functionalized with Py which interacts forward with RGO through pi-pi interactions causing an important modification into the polymer chains conjugation length. (C) 2017 Elsevier B.V. All rights reserved.