• 文献标题:   Selective removal of diethanolamine from methyldiethanolamine solution using chemically reduced single-layer graphene and activated carbon
  • 文献类型:   Article
  • 作  者:   ALI N, PAL P, BANAT F, SRINIVASAKANNAN C
  • 作者关键词:   graphene, activated carbon, alkanolamine, selective adsorption, isotherm
  • 出版物名称:   SEPARATION SCIENCE TECHNOLOGY
  • ISSN:   0149-6395 EI 1520-5754
  • 通讯作者地址:   Khalifa Univ
  • 被引频次:   1
  • DOI:   10.1080/01496395.2018.1549569
  • 出版年:   2019

▎ 摘  要

The adsorption capacity of chemically reduced graphene (CRG) in selective removal of diethanolamine (DEA) from a mixture of methyldiethanolamine (MDEA) in aqueous solutions was evaluated and compared with commercially available activated carbons using batch studies. Four equilibrium isotherm models such as Langmuir, Freundlich, Temkin, and Dubinin-Radushkevish and three different kinetics models such as Pseudo-first order, Pseudo-second order and Intra-particle diffusion were applied. The maximum uptake capacity for DEA using CRG at 296 K (250.0 mg/g) was high compared to two selected activated carbons (1.05 and 0.559 mg/g). The adsorption of DEA was found to be spontaneous and endothermic process with all the adsorbents.