• 文献标题:   Palladium-decorated zinc sulfide/reduced graphene oxide nanocomposites for enhanced visible light-driven photodegradation of indigo carmine
  • 文献类型:   Article
  • 作  者:   AGORKU ES, MAMO MA, MAMBA BB, PANDEY AC, MISHRA AK
  • 作者关键词:   photodegradation, palladium, reduced graphene oxide, zns
  • 出版物名称:   MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
  • ISSN:   1369-8001 EI 1873-4081
  • 通讯作者地址:   Univ S Africa
  • 被引频次:   12
  • DOI:   10.1016/j.mssp.2015.01.033
  • 出版年:   2015

▎ 摘  要

The removal of toxic organic pollutants from wastewater using reduced graphene oxide (rGO) based photocatalysts has dominated recent scientific research. As a result numerous nanomaterials have been studied and used for wastewater remediation. ZnS has been widely studied due to its versatile application in photocatalysis. This study presents the synthesis of a series of Pd-decorated ZnS/rGO nanocomposites by a coprecipitation method. The materials were characterized using Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM)-EDS, UV/visible spectrophotometry, and BET surface area analysis. Indigo carmine (IC) dye (20 ppm) was chosen as a model for organic pollutants and was used to evaluate the photocatalytic performance of the Pd-ZnS/rGO nanocomposites under simulated solar light with varying concentrations of Pd in the host material. Pd-ZnS/rGO showed significant visible light induced photocatalytic activity towards the degradation of IC. Highest photocatalytic activity was observed for the 1.0% Pd-ZnS/rGO sample (k=2.19 x 10(-2) min(-1)). (C) 2015 Elsevier Ltd. All rights reserved.